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which is again an iterative equation which can be solved with a numerical shooting technique according to the same boundary conditions as discussed in Section 8.5. Fig. 8.16 shows the results of calculations of the three lowest energy levels of a spherical GaAs quantum dot surrounded by a finite barrier composed of Ga0.8Al0.2 As, with a sharp boundary. In fact, the formalism above, as that of the circular crosssection quantum wire, is applicable for any radial potential profile V(r), e.g. it is also valid for diffused interfaces. Again, the behaviour of the energies as a function

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of the spatial dimension, as shown in Fig. 8.16, is as expected in confined systems, namely the confinement energy decreases as the size of the system increases.

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Figure 8.18 The probability density of the three lowest energy states in the 300 A spherical quantum dot Fig. 8.17 displays the corresponding radial components of the wave functions. It can be seen that they all have a maximum at the centre of the potential and that as the principal quantum number n increases, then the number of nodes increases. The nature of the states is perhaps better illustrated by considering the charge density. Given that successive increases in the radial coordinate r lead to spherical shells of volume proportional to r2, then the charge density between the radii r and r + Sr is proportional to r2^* (r)ip(r); this is plotted in Fig. 8.18. The lowest energy state, i.e. n = 1, has a single anti-node which is close to half the radius of the potential, while the second has two maxima in the charge density, etc. 8.8 NON-ZERO ANGULAR MOMENTUM STATES The states deduced in the previous section were of the form ^(r), and therefore were analogous to the 's' orbitals akin to hydrogen atoms. However, in atoms there exist other types of state, with the next simplest being that of the 'p' orbitals. These have wave functions of the following form:

// a component - so we need to create a target Port inPort = new InPort(targetComponentPartition); inPortComponent = targetComponent; } // make the connection between the two ports outPortTargetsAdd(inPort); // easy, eh } } }

(see any quantum theory book, e.g. [4], p. 190). These states are clearly not spherically symmetric, and have non-zero angular momenta.

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