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Glazed, coloured terracottas, are very distinctive of the Italian artistic Renaissance and enrich the collections of the world major museums. Art historians are confronted by a rich and composite ensemble of hundreds of objects. PIXE can identify the elemental content as a ngerprint of each glaze and help to identify similarities amongst objects and to strengthen hypotheses on artist attribution. Appropriate analytic procedures42 have been implemented to deal with the nonhomogeneous nature of Renaissance glazes, to treat consistently the three kinds of samples available (polished cross-sections, fragments and whole sculptures), to correlate data from two facilities (ALGAE43 and INFN Florence44 ), to estimate non statistical errors which are between 3 and 8 % for many elements and exceed 10 % only for low Z elements (Na,Al) or for elements well below 1 % in weight. The nature of samples requires some considerations. Plaster, dust or paint, could create a surface layer on whole sculptures and even more on fragments, which are sampled for evident reasons from peripheral dirty areas. The extra layer could exhaust a non-negligible fraction of the total proton range and therefore increase the concentration of contaminant elements, such as Al, K, and Ca in comparison to a polished SEM section. Other discrepancies could be due to the glaze texture. For example the high amounts of CaO found by PIXE on a micro-sample were explained by SEM images. The interface, characterized by the development of newly formed crystals of calcium silicate was exceptionally thick,42 more than 100 m, due to local over- ring inside the Renaissance kiln. A large number of measurements on the same artefact are therefore recommended to avoid possible rdlc pdf 417 PDF417 Barcode Creating Library for RDLC Reports | Generate ...
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